Materials

 

Requests

Below is a selection of recently synthesized materials that are available for collaborative research.

Additional materials are in progress and will be posted as they become available.

For further information please contact: markus.huecker@weizmann.ac.il

WTe2

WTe2 is a semimetallic transition metal dichalogenide that has attracted attention in several ways. As bulk material WTe2 shows a large non-saturating positive magnetoresistance which has been attributed to perfectly balanced electron and hole pockets. At high pressure this positive magnetoresistance disappears while supercoductivity emerges. It was predicted and then experimentally confirmed that WTe2 is a type-II Weyl semimetal in the bulk. WTe2 can be exfoliated down to monolayer thickness where it becomes a quantum spin Hall insulator.

Our WTe2 crystals were grown by self-flux from a Te-rich binary melt using a ratio W:Te of 1:99. Typically our crystals reach RRR values higher than 103, and magnetoresistance ratios at 9T higher than 104. Chemicals: W powder (5N) and Te chunks (6N) from Furuuchi Chemical Corporation, Japan.

 

MnBi2Te4

MnBi2Te4 is a recently discovered antiferromagnetic topological insulator. Structurally, it is derived from topological insulator Bi2Te3 through intercalation of an additional MnTe layer. The Mn moments order ferromagnetically within the planes while the planes couple antiferromagnetically. MnBi2Te4 devices are attracting tremendous attention following the observation of several quantum phenomena such as QAH, axion insulator, and high Chern number QH, depending on the thickness of the device and whether the number of layers is odd or even.

Our crystals were grown by Te-self flux. The two graphs for H II c-axis indicate sharp bulk transitions at the antiferromagnetic ordering temperature, and the critical fields of the spin flop transition as well as the onset of the first magnetization plateau. Chemicals: Mn flakes (4N) , Bi shots (5N), and Te chunks (6N) from Furuuchi Chemical Corporation, Japan.

 

La2CuO4

La2CuO4 is a well known Mott insulator and the parent compound of the La-based 214 cuprate superconductors. It is an important model system for quasi 2D spin S=1/2 Heisenberg antiferromagnetism. Antiferromagnetic correlations in the cuprates are very strong even in the region of the superconducting dome, giving rise to the idea that magnetism may play a role for the formation of superconductivity.

Single crystals were grown with the Laser Floating Zone technique in pure O2 (5N)  at a pressure of 3 atm. Chemicals: La2O3 (99.999%), CuO (99.9995%) from Alfa Aesar.

 

 

 

 

 

 

La2-xBaxCuO4

La2-xBaxCuO4 is famous for being the first high-Tc superconductor, but since has become something like the Rosetta Stone of cuprate science, helping to decipher the role of the various coexisting electronic states. Of particular interest is the region around a charge carrier concentration x=1/8 where superconductivity competes with static charge and spin orders.

Single crystals were grown with the Laser Floating Zone technique in 96% O2 and 4% Ar at a pressure of 3 - 5 atm. The small amount of argon helps suppress the formation of bubbles in the liquid zone which can disrupt stable growth. Crystals with different Ba concentrations are available. Chemicals: La2O3 (99.999%), Ba2CO3 (99.99%), CuO (99.995%) from Alfa Aesar.