Calibrated Pulse-Length Values

Calibrated Pulse-Length Values

Calibrated pulse lengths for NEO-1000 probes

Probe Nucl 90 deg Pulse length (µs) Power level (dB) Remarks
 
 
RT-5-TXI 1H 10.0 -13.25 hard
  13C 13.00 -18.59 hard
  " 25 -18.09 C-C tocsy
  " 50 -12.07 dec, garp
  " 246 -23.65 90deg sp, g4.256
  " 900 -12.23 90deg sp, Q5.1000
  " 154 -24.71 180deg sp, Q3.1000
  " 630 -14.46 180deg sp, Q3.surbop.1
  " 500 -17.89 Crp60 ; Adiabatic inversion
  " 2000 -17.89 Crp60comp.4; Adiabatic refocusing
  15N 39.0 -23.77 hard
  " 220 -8.28 cpd, garp
  2H  150 -18.59 hard
    176 -17.21 dec
 
CP 5-TCI-X,Y,Z 1H     hard
  "     tocsy*
  13C 12   hard
  " 13.14   offres=131ppm
  " 14.23   offres=121ppm
  " 25   C-C tocsy
  " 29.39   offres=131ppm
  " 31.82   offres=121ppm
  "     garp dec
  "      
  " 333   sp, g4
  " 512   sp, g4
  " 256   sp, g3
  " 512   sp, g3
  "     sp, g3 (sel CO dec)
  15N     hard
  " 220   dec, garp
  2H       
 
CP 3-TCI 1H     hard*
  13C     hard
  " 25   C-C tocsy
  "     garp dec 100ppm
  "      
  " 333   sp, g4
  " 512   sp, g4
  " 256   sp, g3
  " 512   sp, g3
  "     sp, g3
  15N     hard
  " 220   dec, garp
  2H      
  2H      

Calibrated pulse lengths for AVIII-800 probes

Probe Nucl 90 deg Pulse length (µs) Power level (dB) Remarks
 
 
CRP-TCI (#38) 1H 14.5 -8.05 hard*
  13C 14.35 -21.06 hard
  " 16.43   offres=131ppm
  " 17.64   offres=122ppm
  " 25 -16.5 C-C tocsy
  " 36.7   offres=131ppm
  " 39.45   offres=122ppm
  " 67 -8.04 dec, garp
  " 333 -19.78 90deg sp, g4.256
  " 333 -18.95 90deg sp, Q5.1000
  " 410 -17.33 90deg sp, Q5.1000
  " 512 -16.00 90deg sp, g4.256
  " 256 -19.15 180deg sp, g3.256
  " 256 -18.60 180deg sp, Q3.1000
  " 310 -16.97 180deg sp, Q3.1000
  " 512 -12.62 180deg sp, Q3.256
  " 620 -10.92 180deg sp, Q3.1000
  " 256 -6.90 sp, sinc.128
  " 256 -8.87 sp, Seduce.100
  15N 47.71 -20.87 hard
  " 190 -8.59 dec, garp
  2H  184 8.2 W hard
    244.5 4.4978 W dec
    433.5 1.5 W dec
 
TXI 1H 10.2   hard*
  " 30   tocsy*
  " 100   roesy*
  " 1000   selective (H2O)
  13C     hard
  " 16.3   offres=132ppm
  " 17.64   offres=122ppm
  " 25   C-C tocsy
  " 36.46   offres=132ppm
  " 39.45   offres=122ppm
  " 60   garp dec 100ppm
  " 67    
  " 333   sp, g4
  " 512   sp, g4
  " 256   sp, g3
  " 512   sp, g3
  " 768   sp, g3 (sel CO dec)
  15N     hard
  " 210   dec, garp
  2H  300    
         
 
QXI 1H     hard*
  13C     hard
  " 16.3   offres=132ppm
  " 17.64   offres=122ppm
  " 25   C-C tocsy
  " 36.46   offres=132ppm
  " 39.45   offres=122ppm
  " 60   garp dec 100ppm
  " 67    
  " 333   sp, g4
  " 512   sp, g4
  " 256   sp, g3
  " 512   sp, g3
  " 768   sp, g3
  15N     hard
  " 210   dec, garp
  2H 300    
  2H 500    

*Depends very much on the sample. Should be calibrated again on the studied sample.
 

Calibrated pulse lengths for NEO-600 probes

Probe Nucl 90 deg Pulse length (µs) Power level (dB) Remarks
 
 
5 mm CRP-TCI 1H   -8.32 hard*
  13C 11.8 -20.49 hard
  " 27 -13.18 C-C tocsy
  " 67 -5.12 dec, garp
  " 210    
  " 333 -16.47 90deg sp, Q5.1000
  " 400 -14.86 90deg sp, Q5.1000
  " 256 -15.75 180deg sp, Q3.1000
  " 310 -14.03 180deg sp, Q3.1000
  " 512   180deg sp, Q3.256
  " 620   180deg sp, Q3.1000
  " 128 -10.0 sp, sinc.128
  " 256   sp, Seduce.100
  15N 36.5 -21.02 hard
  " 170 -7.48 dec, garp
  2H  76.3 -15.8 hard
    463 -0.14 dec
 
1.7 mm CRP TCI 1H 10.2   hard*
  13C     hard
  " 25   C-C tocsy
  " 67    
  15N     hard
  " 210   dec, garp
         
5 mm TXI 1H     hard*
  13C     hard
  " 25   C-C tocsy
  " 60   garp dec 100ppm
  " 67    
  15N     hard
  " 210   dec, garp

*Depends very much on the sample. Should be calibrated again on the studied sample.
 

     

    Calibrated pulse lengths for AV-500 probes

     

    PROBE
    Nucl
    High Power


     
    Low power


     
    remarks
       
    p1 (µs)
    pl1 (dB)
    p1
    (µs)
    pl1(dB)
    		  
     
    BBI 1H 6.8 0      
      13C  13 -2 67 12  
      15N 27 -2 208 16  
      31P 17.8 0 72 12  
     
    BBO 1H  7.5 -4 110 19  
      13C  7 -1      
      31P 7.6 -2      
      15N 10 -4      
     
    TBI 1H 7.3 0      
      13C 13.2 -3 69 11  
      15N 21.5 -4 188 15  
      31P 20.5 -1 72 10  
     
    TXI 1H 3.6 0      
      13C 9.6 -4 70 13  
      15N 27 -4 195 13  
    QNP 1H 11 -6 100 14  
      13C 6 -6      
      31P 8.2 0 100 21  
      19F 10.2 -6      
                 

     

     

      Calibrated pulse lengths for AVIII-400 probes

       

      PROBE
      Nucl
      High Power


       
      Low power


       
      remarks
         
      p1 (µs)
      pl1 (dB)
      p1
      (µs)
      pl1(dB)
      		  
       
      QNP 1H 13  -4 80 14  
        13C  6.2-5.8 -6 80 19  
        31P  6.5 -2 80(90) 15(26)  
        19F  15  -6 80 10  
       
      BB5 1H  9 -4 80 19  
        13C  17 -4      
          14.4 -6      
        2H  11 -4      
        15N  12.6  -4      
        17O  14 -4      
        29Si  9 -4      
        31P          
        51V  7.2 -4      
        119Sn 6.15  -4     no dec.
          5.75  -4      with dec.
        121Sb 8.8 -4      
        127I 12.5 -4      
        195Pt 12  -4      
                   
        13C 18 20W      
        19F 14 12W      
        23Na 11 50W      
                   
       
      BBI 1H 6.7 -3 80 18 ROESY spin-lock 22dB
        13C 13 -6 85 12 100W
          9.6 -3 90 17 300W
              85 16 300W
        15N 26.5 -4 180 13 100W
              200 14 100W
          16 -4 180 18 300W
              200 19 300W
        31P 12 -4      
        29Si 15 -6 130 12 100W
          11.4 -3 80 14 300W
       
      TBI 1H 6.5 -3 80 17 100W
        13C 9 -4     300w
        15N 26 -4     100W
          14(16) -4 190 19 300W
        31P 23.5 -4     100W
       
      BB10 1H          
        17O 28 -4      
        31P 22 -4 100 10  
       
      SEL 1H 7.9 -3      
       
      BBO10 39K 38 -6      
        183W 40 -6      
         
      BBFO 1H 13 18.5W 90 0.411W  
        2H 30 25W      
        11B 16 30W      
        13C 9 64W 70 1.2W  
        14N 15 60W      
        15N 19.5 66.5W 180 0.85W  
        19F 13 30W 70 1.0347W  
        29Si 11.5 65W 180 0.25W  
        31P 13 17W 80 0.45W  
        31P 20 26W 80 1.625W  
        33S 30 60W      
        77Se 12 60W      
                   

       

       

      Calibrated pulse lengths for AVIII-300 probes

       

      PROBE Nucl High Power
             		 Low Power
             		 Remarks
          p1 (µs) pl1 (dB) p1 (µs) pl1 (dB)  
       
      QNP 1H 11 -6 100 14  
        13C 6 -6      
        31P 8.2 0 100 21  
        19F 10.2 -6      
                   
      BB5 1H 10.5 -6 100 17  
        13C 5.5 -3      
        31P 6.7 0      

       

         

        Pulse Calibration Procedures